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ECOLIB DIGITAL REPOSITORY is the institutional repository of National Research and Development Institute for Industrial Ecology ECOIND.
ECOLIB ensures preservation and management of documents and provides access to: articles of the ECOIND researchers published in national and international journals (full-paper/abstract), doctoral theses (abstract), conference and workshop papers, short description of the projects developed from 2006 till present, Proceedings of the International Symposium - Environment and Industry. The digital documents submitted in ECOLIB are indexed in Google Scholar.
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http://hdl.handle.net/123456789/1788| Title: | Graphene quantum dots and Cu(I) liquid crystal for advanced electrochemical detection of doxorubicine in aqueous solutions | Authors: | Motoc, Sorina Schinteie, Bianca Pop, Aniela Negrea, Sorina Claudia Cretu, Carmen Szerb, Elisabeta Manea, Florica |
Affiliations: | “Coriolan Dragulescu” Institute of Chemistry Timisoara of Romanian Academy “Coriolan Dragulescu” Institute of Chemistry Timisoara of Romanian Academy Politehnica University of Timisoara National Research and Development Institute for Industrial Ecology, ECOIND “Coriolan Dragulescu” Institute of Chemistry Timisoara of Romanian Academy “Coriolan Dragulescu” Institute of Chemistry Timisoara of Romanian Academy Politehnica University of Timisoara |
Keywords: | Graphene quantum dots;Liquid crystalline Cu(I) coordination complex;Electrochemical detection;Doxorubicine;C-based paste electrodes | Issue Date: | Oct-2021 | Publisher: | MDPI, Basel, Switzerland. | Abstract: | Two paste electrodes based on graphene quantum dots and carbon nanotubes (GRQD/CNT) and one modified with a homoleptic liquid crystalline Cu(I) based coordination complex (Cu/GRQD/CNT) were obtained and morphostructurally and electrochemically characterized in comparison with simple CNT electrode (CNT) for doxorubicine (DOX) detection in aqueous solutions. GRQD/CNT showed the best electroanalytical performance by differential pulse voltammetry technique (DPV). Moreover, applying a preconcentration step prior to the detection stage, the lowest limit of detection (1 ng/L) and the highest sensitivity (216,105 µA/mg·L−1) in comparison with reported literature data were obtained. Cu/GRQD/CNT showed good results using the multiple pulse amperometry technique (MPA) and a favorable shifting of the potential detection to mitigate potential interferences. Both GRQD-based paste electrodes have a great potential for practical utility in DOX determination in water at trace concentration levels, using GRQD/CNT with DPV and in pharmaceuticals formulations using Cu/GRQD/CNT with MPA. |
Description: | Nanomaterials, 2021, vol. 11, 2788. https://doi.org/10.3390/nano11112788. |
URI: | http://hdl.handle.net/123456789/1788 |
| Appears in Collections: | Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Graphene Quantum Dots and Cu(I) Liquid Crystal.pdf | Article | 3.68 MB | Adobe PDF | View/Open |
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