Cristea, IonutIonutCristeaDinu, Laurentiu RazvanLaurentiu RazvanDinu2017-03-142017-03-142013L : 1843-5831(on-line): 2457-8371http://hdl.handle.net/123456789/387http://www.simiecoind.ro/wp-content/uploads/2015/04/APPLICATION-OF-X-RAY-FLUORESCENCE-SPECTROMETRY.pdfInternational Symposium "The Environment and the Industry" SIMI 2013Volume IIA method for simultaneous analysis of Fe, Mn, Al, Ca, Mg, Cd, Cr, Cu, Hg, Ni, Pb, Zn and As from mine water treatment sludge was developed using an NEX CG - Energy Dispersive X-ray Fluorescence Spectrometer. The XRF analysis results were verified with other consecrated method such AAS and ICP-MS using standardized methodologies, including pretreatment of samples. Good correlation of results between methods was achieved (usually 0.93-0.98). Minimum sample preparation (drying, sieving and prolene cup preparation) is needed, and up to 4 samples can be analyzed per hour. Usual limit of detection for analyzed elements was between 3 and 30 mg/Kg dw, with higher limits for light elements as Mg (384 mg/Kg dw) Al(162 mg/Kg dw). XRF analysis method was successfully used for analysis of some precipitates obtained from mine waters using various precipitation methods. Mine water was sourced from some closed Romanian mines.Energy Dispersive X-ray FluorescenceMine water treatmentHeavy metalsApplication of X-ray fluorescence spectrometry for analysis of sludge frommine water treatmentSymposium Proceedings