RJEEC, Volume 2, no. 2, 2020

This study aimed to develop two analytical methods for the determination of Cr6+ from fixed source emissions, such as the molecular absorption spectrophotometric method (UV-VIS) and the graphite furnace atomization absorption spectrometry method (GTAAS). The first stage in the development of analytical methods involves establishing the optimal operating conditions for, taking air samples, treating them for analysis, and proceeding for analysis, followed by validating the method by determining performance parameters. For both methods is highly recommended, the use of isokinetic sampling with a sampling probe by the heated glass, quartz, or PTFE. The limit of detection and the limit of quantification were concluded to be 12.38µg/m3 and 40µg/m3, respectively for the UV-VIS method and the GTAAS method 0.12 µg/m3 and 0.54 µg/m3 respectively.

In this paper, a comparison is made of the level of air pollution from two brick production lines that apply different technologies, one old and one new more efficient. The main pollutants emitted into the air from the baking of raw bricks in baking kilns are CO, SO2, NO2, HCl, HF and dust. Monitoring of air pollutants was performed with a Teso 350 flue gas analyzer – the automatic method. A Paul Gothe isokinetic sampler was used to take dust particles, HCl, and HF samples, and the analysis was performed in the laboratory using gravimetry and spectrophotometry as analytical techniques. The results of the tests performed showed a reduction in the level of pollution by applying BAT technologies by up to 90% for all monitored pollutants, compared to the pollution produced by an old, non-retechnologized line. At the same time, energy consumption is lower per unit of product, which results in a significant decrease in production costs.