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ICP-EOS method development and validation for Cr(VI) determination in plants

Date issued
2021-12-27
Author(s)
Tenea, Anda Gabriela  
National Research and Development Institute for Industrial Ecology, ECOIND  
Mureseanu, Mihaela  
University of Craiova  
Vasile, Gabriela  
National Research and Development Institute for Industrial Ecology, ECOIND  
Dinu, Cristina  
National Research and Development Institute for Industrial Ecology, ECOIND  
Abstract
The aim of this study was the development and validation of a new inductively coupled plasma optical emission spectrometry (ICP-EOS) method for the determination of Cr(VI) from vegetable samples. The new method was validated entirely by verifying performance parameters (linearity, inter-day and intra-day precision,
limit of detection - LOD, and limit of quantification - LOQ). The vegetable samples, mint, and basil were contaminated with a known amount of K2Cr2O7. Cr(VI) was extracted from the vegetable samples by ultrasound-assisted extraction technique, using 0.1 M Na2CO3 as the extraction medium. The ICP-EOS method proved very sensitive, allowing us to determine up to 3.0 µg/g Cr(VI) in vegetable matrices, which was established as the method LOQ.
Subjects

Cr(VI)

ICP-EOS

Mint

Basil

Speciation

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Lucrare Anda Tenea 2021 Anale Craiova.pdf

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(MD5):d6df8c1c7701a460e26b79746297205e

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